Mit der Synthese von Cyclononatetraenid 3) eriiffnete sich 1963 ein akzeptabler Zugang zu Cyclononatetraenen, doch blieb bisher die Zahl der auf diesem Wege isolierten Verbindungen 1 bescheiden. Die beschrgnkte Anwendung von Cyclononatetraenen in der organischen Synthese hat zwei Ursachen: Einmal wi
β¦ LIBER β¦
Classical anion radical from trans-fused bicyclo[6.1.0]nona-2,4,6-triene
β Scribed by Moshuk, Gordon.; Petrowski, Gary.; Winstein, Saul.
- Book ID
- 127023348
- Publisher
- American Chemical Society
- Year
- 1968
- Tongue
- English
- Weight
- 332 KB
- Volume
- 90
- Category
- Article
- ISSN
- 0002-7863
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Extraction with ethyl acetate or ether and distillation of the crude furnishes pure (2). As shown in the reaction scheme, the overall reaction proceeds via several unisolated intermediates and it has not yet been established whether the cyclization occurs with (la) or ( 1 b). Remarkably, in the pres