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Cis/trans conversion of potassium derivatives of 2- and 4-nitrostilbenes

✍ Scribed by Zori V. Todres


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
416 KB
Volume
441
Category
Article
ISSN
0022-328X

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N-O acyl migration in the N-benzoyl deri
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In a previous Letter 111 the N-O acyl migration of cis-and trans-2--aminomethylcyclohexanol and cis-and trans-2-hydroxymetbylcyclohexylamine derivatives was reported. The present coamnznication deals with the stereospecific synthesis of the analogous cyclopentane derivatives, as well as the examinat

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Equilibrations of the stereoisomeric cis -and trans -2 -t-butyl-4 -hydroxycyclo-hexanones (I and If), catalyzed by hydrogen chloride in benzene solution (Table I), show 'AH", -130 \* 30 Cal/mole; i?S", of log K vs. l/T. -0.13 \* 0.1 eu; from a graph Estimated absolute error limits are given.