✦ LIBER ✦

Equilibration of cis - and trans -2- t -butyl-4-hydroxycyclohexanone

✍ Scribed by Robert D. Stolow; Theodore Groom

Publisher: Elsevier Science
Year: 1968
Tongue: French
Weight: 204 KB
Volume: 9
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)72865-6

No coin nor oath required. For personal study only.

✦ Synopsis

Equilibrations of the stereoisomeric cis -and trans -2 -t-butyl-4 -hydroxycyclo-hexanones (I and If), catalyzed by hydrogen chloride in benzene solution (Table I), show 'AH", -130 * 30 Cal/mole; i?S", of log K vs. l/T.

-0.13 * 0.1 eu; from a graph Estimated absolute error limits are given.

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