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Cis- und trans-2,3-Dimethyl-dibenzobicyclo-[2,2,2]-octadien

✍ Scribed by H. M. Walborsky

Book ID: 102247241
Publisher: John Wiley and Sons
Year: 1953
Tongue: German
Weight: 358 KB
Volume: 36
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19530360605

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✦ Synopsis

A simple five-step conversion of 12-ketosteroids into 11 p-hydroxy compounds (and also 11-ketones) through 11 p, 12B-epoxides is described. The process can be accomplished with high yields, as it is shown in the present paper dealing with the application to hecogenin acetate.

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