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cis-(Malonato-κ2O,O′)bis(2-methylpyridine-κN)platinum(II)

✍ Scribed by Xie, Ming-Jin ;Yu, Yao ;Liu, Wei-Ping ;Hou, Shu-Qian ;Chen, Xi-Zhu


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
937 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


cis-(Malonato-2 O,O')bis(2-methylpyridine-N)platinum(II)


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In the crystal structure of the title compound, [Pt(C~6~H~6~O~4~)(C~6~H~7~N)~2~], the platinum(II) ion is tetracoordinated in a square-planar coordination. The structure involves intramolecular C—H...O hydrogen bonds.

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Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.005 A Ê R factor = 0.045 wR factor = 0.092 Data-to-parameter ratio = 13.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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The title complex, [Co(C 3 H 3 O 4 ) 2 (H 2 O) 2 ], is isostructural with its iron, zinc and magnesium analogues. The molecule has inversion symmetry. The molecules are linked together via O-HÁ Á ÁO hydrogen bonds, leading to a three-dimensional network.

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In the title compound, [Pd II (C 3 H 2 O 4 )(C 3 H 10 N 2 )], the Pd II atom adopts a distorted cis-square-planar geometry. The ligands form two six-membered chelate rings, with propane-1,3-diamine adopting a chair conformation and the malonato ligand a boat conformation. The crystal packing is stab

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Single-crystal X-ray study T = 295 K Mean (C-C) = 0.005 A R factor = 0.041 wR factor = 0.114 Data-to-parameter ratio = 14.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.