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(Malonato-κ2O,O′)(propane-1,3-diamine-κ2N,N′)palladium(II)

✍ Scribed by Odoko, Mamiko ;Okabe, Nobuo


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
187 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, [Pd II (C 3 H 2 O 4 )(C 3 H 10 N 2 )], the Pd II atom adopts a distorted cis-square-planar geometry. The ligands form two six-membered chelate rings, with propane-1,3-diamine adopting a chair conformation and the malonato ligand a boat conformation. The crystal packing is stabilized by a network of N-HÁ Á ÁO and C-HÁ Á ÁO hydrogen bonds.


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The title compound, [Pd II (C 2 O 4 )(C 3 H 10 N 2 )], crystallizes with two unique molecules in the asymmetric unit. The Pd II atom adopts distorted cis-square-planar geometry. The oxalate ligand lies in the coordination plane and the six-membered chelate ring formed by the Pd II atom and the propa

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