The title compound, [Pd II (C 2 O 4 )(C 3 H 10 N 2 )], crystallizes with two unique molecules in the asymmetric unit. The Pd II atom adopts distorted cis-square-planar geometry. The oxalate ligand lies in the coordination plane and the six-membered chelate ring formed by the Pd II atom and the propa
✦ LIBER ✦
(Malonato-κ2O,O′)(propane-1,3-diamine-κ2N,N′)palladium(II)
✍ Scribed by Odoko, Mamiko ;Okabe, Nobuo
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 187 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the title compound, [Pd II (C 3 H 2 O 4 )(C 3 H 10 N 2 )], the Pd II atom adopts a distorted cis-square-planar geometry. The ligands form two six-membered chelate rings, with propane-1,3-diamine adopting a chair conformation and the malonato ligand a boat conformation. The crystal packing is stabilized by a network of N-HÁ Á ÁO and C-HÁ Á ÁO hydrogen bonds.
📜 SIMILAR VOLUMES
(Oxalato-κ2O,O′)(propane-1,3-diamine-κ2N
✍
Odoko, Mamiko ;Okabe, Nobuo
📂
Article
📅
2007
🏛
International Union of Crystallography
🌐
English
⚖ 201 KB
Bis[μ2-N,N′-bis(2-oxidobenzyl)propane-1,
✍
Tatar Yıldırım, Leyla ;Ergun, Ümit
📂
Article
📅
2007
🏛
International Union of Crystallography
🌐
English
⚖ 931 KB
Bis[μ2-2,2′-dimethyl-N,N′-bis(2-oxidoben
✍
Tatar Yıldırım, Leyla ;Atakol, Orhan ;Kavak, Gülten
📂
Article
📅
2007
🏛
International Union of Crystallography
🌐
English
⚖ 880 KB
catena-Poly[[[(propane-1,2-diamine-κ2N,N
✍
Lee, Clare ;Harrison, William T. A.
📂
Article
📅
2007
🏛
International Union of Crystallography
🌐
English
⚖ 439 KB
Bis[N-(isopropylidene)propane-1,3-diami
✍
Curtis, Neil F. ;Robinson, Ward T.
📂
Article
📅
2006
🏛
International Union of Crystallography
🌐
English
⚖ 138 KB
cis-(Malonato-κ2O,O′)bis(2-methylpyridin
✍
Xie, Ming-Jin ;Yu, Yao ;Liu, Wei-Ping ;Hou, Shu-Qian ;Chen, Xi-Zhu
📂
Article
📅
2007
🏛
International Union of Crystallography
🌐
English
⚖ 937 KB
cis-(Malonato-2 O,O')bis(2-methylpyridine-N)platinum(II)