𝔖 Bobbio Scriptorium
✦   LIBER   ✦

cis-Dichlorido(N-cyclohexylpropane-1,3-diamine-κ2N,N′)platinum(II)

✍ Scribed by Xie, Ming-Jin ;Chen, Xi-Zhu ;Liu, Wei-Ping ;Hou, Shu-Qian ;Ye, Qing-Shong

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
472 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The reaction of N-cyclohexylpropane-1,3-diamine with potassium tetrachloroplatinate(II) produced the monomeric title complex, [PtCl 2 (C 9 H 18 N 2 )]. In the asymmetric unit there are two crystallographically independent Pt II complexes, where each Pt II ion is tetracoordinate in a distorted square-planar geometry. N-HÁ Á ÁCl hydrogen bonds between the complexes form a three-dimensional network in the crystal structure.

📜 SIMILAR VOLUMES

Dichlorido[1-(1-naphthylmethyl)-3-(2-pyr
Dichlorido[1-(1-naphthylmethyl)-3-(2-pyridyl)-1H-pyrazole-κ2N2,N3]zinc(II)
✍ Liu, Chun-Sen ;Yan, Li-Fen ;Wang, Jun-Jie 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 564 KB

In the title compound, [ZnCl 2 (C 19 H 15 N 3 )], the Zn II atom is four-coordinated by two N atoms from the 1-(1-naphthylmethyl)-3-(2-pyridyl)-1H-pyrazole (L) ligand and two terminal Cl atoms in a distorted tetrahedral coordination environment. In the crystal structure, inversion-related Zn II mono

Dichlorido(N,N′-dibenzylideneethane-1,2-
Dichlorido(N,N′-dibenzylideneethane-1,2-diamine-κ2N,N′)[(2,2-dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanolato)-κ2O,O′]titanium(IV)
✍ Chen, Chien-An ;Chiang, Liang-Ying ;Gau, Han-Mou 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 450 KB

The title compound, [TiCl~2~(C~31~H~28~O~4~)(C~16~H~16~N~2~)], is a titanium(IV) complex of the bidentate 2,2-dimethyl-α,α,α′,α′-tetraphenyl-1,3-dioxolane-4,5-dimethanolate (TADDOLate) ligand containing also two chloride ions and a bidentate neutral __N__,__N__′-dibenzylideneethane-1,2-diamine ligan

(Oxalato-κ2O,O′)(propane-1,3-diamine-κ2N
(Oxalato-κ2O,O′)(propane-1,3-diamine-κ2N,N′)palladium(II)
✍ Odoko, Mamiko ;Okabe, Nobuo 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 201 KB

The title compound, [Pd II (C 2 O 4 )(C 3 H 10 N 2 )], crystallizes with two unique molecules in the asymmetric unit. The Pd II atom adopts distorted cis-square-planar geometry. The oxalate ligand lies in the coordination plane and the six-membered chelate ring formed by the Pd II atom and the propa

(Malonato-κ2O,O′)(propane-1,3-diamine-κ2
(Malonato-κ2O,O′)(propane-1,3-diamine-κ2N,N′)palladium(II)
✍ Odoko, Mamiko ;Okabe, Nobuo 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 187 KB

In the title compound, [Pd II (C 3 H 2 O 4 )(C 3 H 10 N 2 )], the Pd II atom adopts a distorted cis-square-planar geometry. The ligands form two six-membered chelate rings, with propane-1,3-diamine adopting a chair conformation and the malonato ligand a boat conformation. The crystal packing is stab