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Dichlorido[1-(1-naphthylmethyl)-3-(2-pyridyl)-1H-pyrazole-κ2N2,N3]zinc(II)

✍ Scribed by Liu, Chun-Sen ;Yan, Li-Fen ;Wang, Jun-Jie

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
564 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [ZnCl 2 (C 19 H 15 N 3 )], the Zn II atom is four-coordinated by two N atoms from the 1-(1-naphthylmethyl)-3-(2-pyridyl)-1H-pyrazole (L) ligand and two terminal Cl atoms in a distorted tetrahedral coordination environment. In the crystal structure, inversion-related Zn II mononuclear units are linked to form dimers throughstacking interactions between the pyridine and pyrazole rings, the centroid-centroid distance being 3.5166 (19) A ˚. The dimers are interlinked to form a chain along the a axis by C-HÁ Á Á interactions involving both benzene rings of the L ligand.

📜 SIMILAR VOLUMES

[1-Benzyl-3-(2-pyridyl)-1H-pyrazole-κ2N2
[1-Benzyl-3-(2-pyridyl)-1H-pyrazole-κ2N2,N3]dichloridopalladium(II)
✍ Liu, Chun-Sen ;Shi, Xue-Song 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 311 KB

In the title compound, [PdCl 2 (C 15 H 13 N 3 )], the Pd II center is four-coordinated by two N-atom donors from one 1-benzyl-3-(2-pyridyl)-1H-pyrazole ligand and by two Cl atoms in a distorted square-planar coordination environment. In the crystal structure, adjacent Pd II mononuclear units are lin

cis-Dichlorido(N-cyclohexylpropane-1,3-d
cis-Dichlorido(N-cyclohexylpropane-1,3-diamine-κ2N,N′)platinum(II)
✍ Xie, Ming-Jin ;Chen, Xi-Zhu ;Liu, Wei-Ping ;Hou, Shu-Qian ;Ye, Qing-Shong 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 472 KB

The reaction of N-cyclohexylpropane-1,3-diamine with potassium tetrachloroplatinate(II) produced the monomeric title complex, [PtCl 2 (C 9 H 18 N 2 )]. In the asymmetric unit there are two crystallographically independent Pt II complexes, where each Pt II ion is tetracoordinate in a distorted square