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Circular dichroisms of tris(propylenediamine)cobalt(III) ions

✍ Scribed by Kazuko Ogino; Kanji Murano; Junnosuke Fujita

Publisher
Elsevier Science
Year
1968
Weight
132 KB
Volume
4
Category
Article
ISSN
0020-1650

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Circular dichroism of cobalt(III) comple
Circular dichroism of cobalt(III) complexes: dependence on the outer sphere configuration
✍ Lucjan Dubicki; James Ferguson; Rodney J. Geue; Alan M. Sargeson πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 English βš– 347 KB

The smgle crystal az~al CD of three Co(ii1) complekes has been measured between 295 and 9 K. For A-Co (sepulchrate) (NO313 the rotatlonal strength R('Tl(E) -lA1) decreases from =l I X lOdo c.g.s. umts at 295 K to ~0 at 80 K. The main features of the smgle crystal CD spectra can be evplamed by a Stai