Circular dichroism spectrum and absolute configuration of tris(acetylacetonato) chromium(III)
✍ Scribed by Bengt Nordén
- Publisher
- Elsevier Science
- Year
- 1975
- Weight
- 276 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0020-1650
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The correlation between the absolute configuration and CD of aza‐ and thiaflavanone (1, 2) is discussed: the 2__R__ configuration for the laevorotatory enantiomers has been established by a comparison of their CD data with those of (__S__)‐(−)‐3. For the Cotton effect within the n → π^\
i v i t i e s o f sterically-hindered b i a r y l s have been extensively investigated, both from experimental and theoretical points of view, t o establish the absolute configuration o f dissymetric b i p h e n y l s l l l , l , l ' -b i n a p h t h y l s / Z l and 1.1 '-bianthryls/3/. no example a
The absolute configuration of the (À)-enantiomer of mirtazapine was determined by means of vibrational circular dichroism (VCD). The observed VCD of (À)-mirtazapine showed excellent correlation with the calculated VCD of the (R)-enantiomer. This is in agreement with the absolute configuration as det