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Circular dichroism of cobalt(III) complexes: dependence on the outer sphere configuration

✍ Scribed by Lucjan Dubicki; James Ferguson; Rodney J. Geue; Alan M. Sargeson

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
347 KB
Volume
74
Category
Article
ISSN
0009-2614

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✦ Synopsis

The smgle crystal az~al CD of three Co(ii1) complekes has been measured between 295 and 9 K. For A-Co (sepulchrate) (NO313 the rotatlonal strength R('Tl(E) -lA1) decreases from =l I X lOdo c.g.s. umts at 295 K to ~0 at 80 K. The main features of the smgle crystal CD spectra can be evplamed by a Stailc couplmg model of optical acflvlty.

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Calculation of the circular dichroism of
Calculation of the circular dichroism of double-helical nucleic acids. III. Dependence of the results on the choice of wave functions for purines and pyrimidines
✍ David S. Studdert; Robert C. Davis 📂 Article 📅 1974 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 559 KB

## Abstract The circular dichroism of double‐helical nucleic acids was calculated using three different sets of wave functions for the purine and pyrimidine chromophores. Different wave functions give qualitatively the same types of spectra. Quantitatively, the differences are very substantial. How