## Abstract The conformational transition of polyβLβtyrosine in 0.1__M__ KCl was investigated by ORD and infrared spectroscopy, potentiometric titration, and sedimentation velocity experiments. It is shown that the fully ordered conformer is obtained by slow titration of the random coil with 0.1__N
Circular dichroic spectrum of poly-L-tyrosine in aqueous solution
β Scribed by S. Friedman; P.O.P. Ts'o
- Book ID
- 118852542
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 343 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0006-291X
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The circular dichroic spectrum of poly(Tyr,TyrBr) in trimethylphosphate from 180 to 320 nm is found to be a linear function of composition from 25 to 68% TyrBr, and the spectra of the Tyr and TyrBr components are resolved. For Tyr the resolved spectrum is in agreement with available CD
## Abstract Titration of an aqueous solution of sodium polyβ__L__βglutamate with a strong acid usually produces turbidity and precipitation before the equivalence point is reached. In 1__M__ sodium __p__βtoluenesulfonate and 1__M__ sodium methylcyclohexanesulfonate aggregation was delayed for days
## Synopsis Aqiieoris solritions of poly-1,-tyrosine were studied by potentiometric titrations, lightsrat,teririg measrirements, and infrared spectroscopy in order to characterize the conformational changes the macromolecules exhibit when the hydrogen-ion concentration of the solutions is varied.
The absorption and circular dichroism spectra of the 1:l copolymer (L-LYS, L-Tyr), have been investigated in aqueous solutions at pH ranging from 3 to 13. The spectral patterns indicate that the fully charged polyampholyte assumes a nonperiodic conformation on the acid and basic sides of the isoelec