Chromono[2,3-b] pyrrolin-2-one
✍ Scribed by Prof. Dr. Fritz Eiden; Wilhelm Hirschmüller
- Publisher
- John Wiley and Sons
- Year
- 1978
- Tongue
- English
- Weight
- 292 KB
- Volume
- 311
- Category
- Article
- ISSN
- 0365-6233
No coin nor oath required. For personal study only.
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## Abstract Bei der Behandlung des tetrachlorsubstituierten Amids **1** mit Methylat (1:10) in Methanol entsteht das chlorfreie Pyrrolinon **5**. Die Reaktion verläuft über das Allen **2** und das Methanol‐addukt **3**. Nach dem gleichen Prinzip liefern die Allen‐Aminaddukte **4** mit Methylat bei
The chiral title compound, C 8 H 9 NO 4 , crystallizes in the noncentrosymmetric space group P2 1 2 1 2 1 , but in the absence of an atom with significant anomalous dispersion, the absolute configuration could not be determined. The H atoms in both methyl groups are eclipsed with respect to the C O
## Abstract The spectra of Δ^3^‐ and Δ^4^‐pyrrolin‐2‐one were analysed and the sign of all the coupling constants determined by tickling and triple resonance experiments. A positive allylic interaction (__J__~xz~ in **2**) is reported and four‐bond couplings are discussed in particular. Deuterium e