Fragmentation of Homoallylic Alkoxides.
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Roger L. Snowden
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Article
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1983
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John Wiley and Sons
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German
β 456 KB
## Abstract The potassium 2βsubstituted bicyclo[2.2.1]heptβ5βenβ2βalkoxides derived from alcohols **2β9** at 30Β° in hexamethylphosphoric triamide (HMPA) afford 1β(3β²βcyclopentenyl)β2βalkanones **10β19** __via__ heterolytic C(1), C(2)βallylic bond cleavage in the substrate alkoxide followed by intra