𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Chromium(VI) oxidation of tertiary unsaturated alcohols. Oxidative fragmentation of 2-substituted bicyclo[2.2.1]hept-5-en-2-ols

✍ Scribed by Waddell, Thomas G.; Carter, April D.; Miller, Tod J.; Pagni, Richard M.


Book ID
111650634
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
434 KB
Volume
57
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Fragmentation of Homoallylic Alkoxides.
✍ Roger L. Snowden πŸ“‚ Article πŸ“… 1983 πŸ› John Wiley and Sons 🌐 German βš– 456 KB

## Abstract The potassium 2‐substituted bicyclo[2.2.1]hept‐5‐en‐2‐alkoxides derived from alcohols **2–9** at 30Β° in hexamethylphosphoric triamide (HMPA) afford 1‐(3′‐cyclopentenyl)‐2‐alkanones **10–19** __via__ heterolytic C(1), C(2)‐allylic bond cleavage in the substrate alkoxide followed by intra