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Double bond isomerization of 5-vinylbicyclo[2.2.1]hept-2-ene to 5-ethylidenebicyclo[2.2.1]hept-2-ene over alkaline earth oxides

โœ Scribed by Kabashima, Hajime ;Tsuji, Hideto ;Hattori, Hideshi


Book ID
112684764
Publisher
Springer
Year
1996
Tongue
English
Weight
226 KB
Volume
58
Category
Article
ISSN
0133-1736

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Irradiation of 5-dicyanomethylenebicyclo[2.2.l]hept-2-ene induces new types of photoreactions, i.e., unprecedented skeletal rearrangement leading to 7,7-dicyano-6-methylenebicyclo[3.l.l]hept-2-ene, and novel 1,3-carbon shifts to bicyclo[3.2.0]-and bicyclo[4.l.O]heptene.