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Photoreaction of 5-dicyanomethylenebicyclo[2.2.1]hept-2-ene

โœ Scribed by Tsutomu Kumagai; Hisashi Honda; Toshio Mukai

Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
250 KB
Volume
26
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Irradiation of 5-dicyanomethylenebicyclo[2.2.l]hept-2-ene induces new types of photoreactions, i.e., unprecedented skeletal rearrangement leading to 7,7-dicyano-6-methylenebicyclo[3.l.l]hept-2-ene, and novel 1,3-carbon shifts to bicyclo[3.2.0]-and bicyclo[4.l.O]heptene.

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## Abstract The three title monomers were polymerized using a variety of Ruโ€, Irโ€, Moโ€, Wโ€ and Reโ€based metathesis catalyst systems to yield polymers having a wide range of __cis__ double bond contents in each case. The ^13^C NMR spectra of the polymers were interpreted in terms of __cis/trans__, h