The structure of the title compound (I) C 13 H 18 O 4 contains three rings in a bicyclo[2.2.1] system (two five-membered rings and one six-membered ring).
endo-Bicyclo[2.2.1]hept-2-ene-5,6-dimethylene bis(p-toluenesulfonate)
✍ Scribed by Ren, Xiao-Hong ;Sun, Li-Li ;Guo, Yu-Ping ;Wang, Fei ;Qi, Zuo-Jun
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 93 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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## Abstract The three title monomers were polymerized using a variety of Ru‐, Ir‐, Mo‐, W‐ and Re‐based metathesis catalyst systems to yield polymers having a wide range of __cis__ double bond contents in each case. The ^13^C NMR spectra of the polymers were interpreted in terms of __cis/trans__, h
The title compound, C 16 H 18 O 3 S, an endo-cycloadduct isomer, was obtained from the Diels-Alder reaction of (E)-1-(phenylsulfonyl)pent-3-en-2-one with cyclopentadiene catalysed by a chiral titanium reagent. The crystal structure confirms the absolute streochemistry.
## Abstract For Abstract see ChemInform Abstract in Full Text.
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