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Ring-opening polymerization of fluorine substituted bicyclo [2,2,1] hept-2-enes and -hepta-2,5-dienes

โœ Scribed by W.J. Feast; B. Wilson


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
196 KB
Volume
20
Category
Article
ISSN
0032-3861

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Metathesis ring opening polymerization o
โœ Lamies A. Shahada; W.James Feast ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 254 KB

Abstraet--5,6-Bis(chloromethyl)bicyclo[2.2.1]hepta-2-ene undergoes ring opening metathesis polymerization to give poly{1,4-[2,3-bis(chloromethyl)-cyclopentylene] vinylene}. Initiation with MoCIs/MeaSn derived catalyst gives atactic polymer with predominantly trans vinylenes, whereas initiation with