Choice of reduction for the asymmetric top Hamiltonian in HNO3
β Scribed by J.H. Carpenter
- Book ID
- 103200681
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 190 KB
- Volume
- 111
- Category
- Article
- ISSN
- 0022-2852
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π SIMILAR VOLUMES
The published ground state molecular parameters of diazomethane and ketene suggest a breakdown of the standard Watson-type rotational Hamiltonian due to resonant interactions between the ground state rotational levels and some levels in an excited vibrational state. It is shown that the effective ro
The reduction of the effective Hamiltonian has been derived for C 3v symmetric top molecules in the v t = 1 state with extension to nuclear quadrupole coupling. The theory has been applied to the hyperfine structures of rotational transitions observed for AsF 3 (v 4 = 1) [H.
A breakdown of the standard Watson-type rotational Hamiltonian was suggested for a molecule with H 2 XYZ structure [S Λ. Urban and K. M. T. Yamada, J. Mol. Spectrosc. 160, 279-288 (1993)]. This breakdown is due to a near-resonant interaction between the ground state rotational levels and rotational