✦ LIBER ✦

A Breakdown of the Watson-Type Hamiltonian for Some Asymmetric Top Molecules

✍ Scribed by S. Urban; K.M.T. Yamada

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 421 KB
Volume: 160
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.1993.1175

No coin nor oath required. For personal study only.

✦ Synopsis

The published ground state molecular parameters of diazomethane and ketene suggest a breakdown of the standard Watson-type rotational Hamiltonian due to resonant interactions between the ground state rotational levels and some levels in an excited vibrational state. It is shown that the effective rotational Hamiltonian in its standard power-series expansion converges only within a limited range of rotational quantum numbers. For given magnitudes of centrifugal distortion parameters (C_{s}^{\alpha \beta \beta}), the range of convergence is determined by the relative values of rotational constants and normal frequencies. (c) 1993 Academic Press. Inc.

📜 SIMILAR VOLUMES

A Breakdown of the Watson-Type Hamiltoni

A Breakdown of the Watson-Type Hamiltonian for Some Asymmetric-Top Molecules: The Case of the Spin-Multiplet State

✍ K. Yokoyama; W.C. Lineberger; K.M.T. Yamada 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 163 KB

A breakdown of the standard Watson-type rotational Hamiltonian was suggested for a molecule with H 2 XYZ structure [S ˇ. Urban and K. M. T. Yamada, J. Mol. Spectrosc. 160, 279-288 (1993)]. This breakdown is due to a near-resonant interaction between the ground state rotational levels and rotational

A new scheme for the reduction of the ef

A new scheme for the reduction of the effective rotational Hamiltonian of a symmetric top-type molecule in a nondegenerate vibrational state

✍ A.V. Burenin 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 335 KB

Effective Hamiltonian for the E-Type Vib

Effective Hamiltonian for the E-Type Vibrational-State of a Rigid Molecule with a Point Symmetry Group C3v

✍ A.V. Burenin 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 220 KB

A complete expression of the effective Hamiltonian, and of the generators of its transformation to the reduced form, is considered as a Taylor series in dynamic variables for the \(E\)-type vibrational state of a rigid molecule with a point symmetry group \(C_{3 \mathrm{v}}\). The suggested reductio

Solid-State Amplified Spontaneous Emissi

Solid-State Amplified Spontaneous Emission in Some Spiro-Type Molecules: A New Concept for the Design of Solid-State Lasing Molecules

✍ Nicklas Johansson; Josef Salbeck; Jacqueline Bauer; Frank Weissörtel; Per Bröms; 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 181 KB 👁 1 views