In the title complex, [NiCl(C 24 H 40 BN 6 )], the Ni atom is coordinated by three N atoms, with the typical facial arrangement imposed by trispyrazolylborate ligands, and a chloride ligand in a distorted tetrahedral geometry. A structure of the title complex was previously reported in a lower symme
Chloro[hydridotris(3-tert-butyl-5-methylpyrazolyl)borato]cobalt(II)
✍ Scribed by Ferrence, Gregory M. ;Beitelman, Adam D.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 196 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Benzoato[hydridotris(3,5-methylphenylpyrazolyl)borato-j 3 N,N 0 0 0 ,N 0 0 00 0 0 ]zinc(II)
Reaction of potassium hydridotris(5-methyl-3-phenylpyrazoly)borate with copper(II) acetate in methanol at room temperature gives the title compound, [Cu(C 30 H 28 BN 6 )-(C 2 H 3 O 2 )]. The Cu atom is five-coordinated by three N atoms from pyrazolyl groups and two O atoms from the acetate ligand.
In the title compound, [Zn(C~30~H~28~BN~6~)(C~4~H~3~N~2~O~3~)]·CH~3~OH, the Zn^II^ atom is coordinated in a tetrahedral geometry by three N atoms from the pyrazolyl groups of the tripodal ligand, and by one O atom from a barbiturate anion.
Single-crystal X-ray study T = 100 K Mean '(C±C) = 0.003 A Ê R factor = 0.061 wR factor = 0.150 Data-to-parameter ratio = 16.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, C 20 H 22 ClN 3 O 4 , the dihedral angle between the benzotriazole plane and the benzene plane is 38.2 (7) . Intramolecular O-HÁ Á ÁO and O-HÁ Á ÁN hydrogen bonds are present.