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Chlorine-photosensitized oxidations of chloroethanes and chloroethylenes in the gas phase

✍ Scribed by L. Bertrand; L. Exsteen-Meyers; J. A. Franklin; G. Huybrechts; J. Olbregts

Publisher
John Wiley and Sons
Year
1971
Tongue
English
Weight
366 KB
Volume
3
Category
Article
ISSN
0538-8066

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✦ Synopsis

Long-chain chlorine-photosensitized oxidation has been observed in the gas phase at about 355'K for 1,1,2,2-and 1,1,1,2-C~H~C14, CZHClS, and CzC14 but not for CzHe, 1,2-CzH4C12, I,l,I-C2H3C13, CzH4, and 1,2-CzHzCIz. This is shown to depend on the exothermicity of the dissociation of the chloroethoxy radicals which must be involved in each reaction system.

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