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Evidence for a biphotonic process in the mercury-photosensitized decomposition of ethylene oxide in the gas phase

✍ Scribed by George R. De Maré

Publisher
Elsevier Science
Year
1977
Weight
421 KB
Volume
7
Category
Article
ISSN
0047-2670

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Disproportionation-combination ratios of
Disproportionation-combination ratios of small alkyl radicals formed by the mercury-photosensitized hydrogenation of olefins in the gas phase
✍ W. E. Falconer; W. A. Sunder 📂 Article 📅 1971 🏛 John Wiley and Sons 🌐 English ⚖ 659 KB

Disproportionation-combination ratios have been obtained for small alkyl radicals produced in the mercury-photosensitized hydrogenation of ethylene, propylene, butene-1, butene-2, and isobutene. For conditions favoring thermalized radicals, kd/k, (ethyl, ethyl) = 0.14, kd/k, (isopropyl, isopropyl) =