Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.012 A Ê R factor = 0.044 wR factor = 0.102 Data-to-parameter ratio = 8.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Chlorido[4,5-dichloro-1,2-bis(2-pyridylcarboxamido)benzene(2–)](dimethylformamide)manganese(III)
✍ Scribed by Liang, Lei ;Qu, Yan-Yang ;Yang, Li ;Zhou, Xiang-Ge
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 125 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.004 A Ê R factor = 0.040 wR factor = 0.120 Data-to-parameter ratio = 16.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, C 6 H 2 Cl 2 N 2 O, the two nitro groups are twisted away from the plane of the aromatic ring. Intermolecular short ClÁ Á ÁO and ClÁ Á ÁCl contacts are observed in the crystal structure.
Tetraethylammonium dichloro[N,N 0 0 0 -(4,5-dichloro-1,2-phenylene)bis(pyridine-2-carboxamidato)]chromate(III)
The cation of the title compound, [Ir~2~ClH~2~(C~6~H~5~S)~2~(C~48~H~40~P~2~)~2~]Cl·2C~2~H~4~Cl~2~, exists as a bridged bifacial octahedral dinuclear iridium structure with __C__ ~2~ symmetry (Cl lies on the rotation axis). The coordination environment of the Ir atom can be described as highly distor