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Chiral sulfoxides in the enantioselective allylation of aldehydes with allyltrichlorosilane

โœ Scribed by Rowlands, Gareth J.; Kentish Barnes, William

Book ID
121349871
Publisher
Royal Society of Chemistry
Year
2003
Tongue
English
Weight
93 KB
Volume
21
Category
Article
ISSN
1359-7345

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๐Ÿ“œ SIMILAR VOLUMES

Asymmetric allylation of aldehydes with
Asymmetric allylation of aldehydes with allyltrichlorosilane promoted by chiral sulfoxides
โœ Antonio Massa; Andrei V. Malkov; Pavel Koฤovskรฝ; Arrigo Scettri ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 68 KB

Allylation of aldehydes with allyltrichlorosilane in the presence of sulfoxides is reported. The use of excess of (R)-methyl-p-tolylsulfoxide resulted in the formation of the corresponding homoallylic alcohols in good yields and moderate enantiomeric excesses.