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Asymmetric allylation of aldehydes with allyltrichlorosilane promoted by chiral sulfoxides

✍ Scribed by Antonio Massa; Andrei V. Malkov; Pavel Kočovský; Arrigo Scettri

Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
68 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis

Allylation of aldehydes with allyltrichlorosilane in the presence of sulfoxides is reported. The use of excess of (R)-methyl-p-tolylsulfoxide resulted in the formation of the corresponding homoallylic alcohols in good yields and moderate enantiomeric excesses.

📜 SIMILAR VOLUMES

Enantioselective Allylation of Aldehydes
Enantioselective Allylation of Aldehydes with Allyltrichlorosilane Promoted by New Chiral Dipyridylmethane N-Oxides.
✍ Giorgio Chelucci; Nicola Belmonte; Maurizio Benaglia; Luca Pignataro 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 21 KB 👁 1 views

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