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Chiral sulfoxides in the enantioselective allylation of aldehydes with allyltrichlorosilane: a kinetic study

โœ Scribed by Monaco, Guglielmo; Vignes, Chiara; De Piano, Francesco; Bosco, Assunta; Massa, Antonio


Book ID
120975426
Publisher
Royal Society of Chemistry
Year
2012
Tongue
English
Weight
507 KB
Volume
10
Category
Article
ISSN
1477-0520

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๐Ÿ“œ SIMILAR VOLUMES


Asymmetric allylation of aldehydes with
โœ Antonio Massa; Andrei V. Malkov; Pavel Koฤovskรฝ; Arrigo Scettri ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 68 KB

Allylation of aldehydes with allyltrichlorosilane in the presence of sulfoxides is reported. The use of excess of (R)-methyl-p-tolylsulfoxide resulted in the formation of the corresponding homoallylic alcohols in good yields and moderate enantiomeric excesses.