Chiral pyrophosphites—synthesis and application as ligands in Rh(I)-catalyzed asymmetric hydrogenation
✍ Scribed by Andrei Korostylev; Detlef Selent; Axel Monsees; Cornelia Borgmann; Armin Börner
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 166 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0957-4166
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📜 SIMILAR VOLUMES
A series of new chiral mono-or bidentate phosphorus ligands were efficiently prepared through a key intermediate (S)-4-chloro-4,5-dihydro-3H-4-phosphacyclohepta[2,1-a;3,4-a%]binaphthalene and its derivatives. These ligands were applied in the Rh-catalyzed asymmetric hydrogenation of a-dehydro amino
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