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Chiral P*-monodentate phosphite ligand for Pd-catalysed asymmetric allylation reactions

✍ Scribed by Konstantin N. Gavrilov; Vasily N. Tsarev; Sergey E. Lyubimov; Alexei A. Shyryaev; Sergey V. Zheglov; Oleg G. Bondarev; Vadim A. Davankov; Anzhelika A. Kabro; Sergey K. Moiseev; Valery N. Kalinin

Book ID: 111730351
Publisher: Royal Society of Chemistry
Year: 2003
Tongue: English
Weight: 119 KB
Volume: 13
Category: Article
ISSN: 0959-9436
DOI: 10.1070/mc2003v013n03abeh001745

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## Abstract A family of monodentate polystyrene‐supported phosphites, phosphoramidites and phosphanes has been prepared and evaluated as ligands in rhodium‐catalysed asymmetric hydrogenation and palladium‐catalysed asymmetric allylic alkylation. The supported ligands yielded active and enantioselec