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Chiral induction in a biomimetic olefin cyclization

✍ Scribed by Hideyuki Takenaka; Tomohiro Sato; Mugio Nishizawa

Book ID
104229819
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
152 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis

Chiral induction has been achieved during a biomimetic cyclization of a chiral perillene derivatives in maximum 76% diastereomeric excess. The absolute configuration of the predominant products are established by X-ray diffraction study and chemical transformations.

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