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Biomimetic polyene cyclizations - asymmetric induction in the cyclization of a chiral dienic imine

โœ Scribed by Gilles Demailly; Guy Solladie


Book ID
108380266
Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
317 KB
Volume
21
Category
Article
ISSN
0040-4039

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Chiral induction in a biomimetic olefin
โœ Hideyuki Takenaka; Tomohiro Sato; Mugio Nishizawa ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 152 KB

Chiral induction has been achieved during a biomimetic cyclization of a chiral perillene derivatives in maximum 76% diastereomeric excess. The absolute configuration of the predominant products are established by X-ray diffraction study and chemical transformations.