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Biomimetic polyene cyclizations. Asymmetric induction during the acid-catalyzed cyclization of chiral imines

โœ Scribed by Demailly, Gilles; Solladie, Guy


Book ID
126816401
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
936 KB
Volume
46
Category
Article
ISSN
0022-3263

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Asymmetric cyclization of unsaturated al
โœ Soichi Sakane; Keiji Maruoka; Hisashi Yamamoto ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 254 KB

A highly enantioselective cyclization of prochiral unsaturated aldehydes has been accomplished with a chiral zinc reagent derived from dimethylzinc and (R)-(+)-l,l'-bi-2-naphthol. Of the available methods for constructing multicarbocyclic structures, cationic polyolefin cyclization, a synthetic str