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Chiral Co(iii)(salen)-catalysed hydrolytic kinetic resolution of racemic epoxides in ionic liquids

✍ Scribed by Rim Oh, Chun; Joon Choo, Dong; Ho Shim, Woo; Hoon Lee, Dong; Joo Roh, Eun; Lee, Sang-gi; Eui Song, Choong

Book ID: 121676199
Publisher: Royal Society of Chemistry
Year: 2003
Tongue: English
Weight: 101 KB
Volume: 9
Category: Article
ISSN: 1359-7345
DOI: 10.1039/B301490H

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## Abstract Enantiomerically pure epoxides (99%, ee) and diols (98%, ee) from racemic epichlorohydrin, 1,2‐epoxypropane, 1,2‐epoxyhexane, 1,2‐epoxyoctane, and 1,2‐epoxydodecane were obtained in 2–12 h by hydrolytic kinetic resolution (HKR) using the recyclable dimeric homochiral Co(III)–salen compl