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Chiral Co(III)(salen)-Catalyzed Hydrolytic Kinetic Resolution of Racemic Epoxides in Ionic Liquids.

โœ Scribed by Chun Rim Oh; Dong Joon Choo; Woo Ho Shim; Dong Hoon Lee; Eun Joo Roh; Sang-gi Lee; Choong Eui Song


Publisher
John Wiley and Sons
Year
2003
Weight
126 KB
Volume
34
Category
Article
ISSN
0931-7597

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## Abstract Enantiomerically pure epoxides (99%, ee) and diols (98%, ee) from racemic epichlorohydrin, 1,2โ€epoxypropane, 1,2โ€epoxyhexane, 1,2โ€epoxyoctane, and 1,2โ€epoxydodecane were obtained in 2โ€“12 h by hydrolytic kinetic resolution (HKR) using the recyclable dimeric homochiral Co(III)โ€“salen compl