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Cooperative Catalysis in the Hydrolytic Kinetic Resolution of Epoxides by Chiral [(salen)Co(III)] Complexes Immobilized on Gold Colloids

✍ Scribed by Thomas Belser; Eric N. Jacobsen


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
387 KB
Volume
350
Category
Article
ISSN
1615-4150

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Cooperative Activation in the Hydrolytic
✍ Sander J. Wezenberg; Arjan W. Kleij 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 274 KB 👁 1 views

## Abstract A chiral, bimetallic cobalt(III)salen‐calix[4]arene hybrid structure was prepared and tested in the hydrolytic kinetic resolution (HKR) of racemic epoxides. Kinetic studies have revealed that the two catalytic units on the upper rim of the calixarene scaffold are able to activate the re