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Enhanced Cooperative Activation Effect in the Hydrolytic Kinetic Resolution of Epoxides on [Co(salen)] Catalysts Confined in Nanocages

✍ Scribed by Hengquan Yang; Lei Zhang; Lin Zhong; Qihua Yang; Can Li


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
157 KB
Volume
46
Category
Article
ISSN
0044-8249

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Cooperative Activation in the Hydrolytic
✍ Sanderβ€…J. Wezenberg; Arjanβ€…W. Kleij πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 274 KB πŸ‘ 1 views

## Abstract A chiral, bimetallic cobalt(III)salen‐calix[4]arene hybrid structure was prepared and tested in the hydrolytic kinetic resolution (HKR) of racemic epoxides. Kinetic studies have revealed that the two catalytic units on the upper rim of the calixarene scaffold are able to activate the re