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Chiral Bis(η 5 :η 1 -pentafulvene)titanium Complexes

✍ Scribed by Diekmann, Mira; Bockstiegel, Geert; Lützen, Arne; Friedemann, Marion; Saak, Wolfgang; Haase, Detlev; Beckhaus, Rüdiger


Book ID
125332227
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
360 KB
Volume
25
Category
Article
ISSN
0276-7333

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Cationic ansa-(η5-Cyclopentadienyl)(η6-a
✍ Patrick J. W. Deckers; Arjan J. van der Linden; Auke Meetsma; Bart Hessen 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 252 KB 👁 1 views

The half-sandwich titanium trimethyl complex (η 5 -C 5 H 4 CMe 2 Ar)TiMe 3 (Ar = 3,5-Me 2 C 6 H 3 ) reacts with the Lewis acid B(C 6 F 5 ) 3 to give the ionic Ti IV ansa-cyclopentadienyl-arene complex [(η 5 ,η 6 -C 5 H 4 CMe 2 Ar)TiMe 2 ]-[MeB(C 6 F 5 ) 3 ]. In bromobenzene solvent, addition of more