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Chiral aminal termplates 61. Diastereoselectivity of hydrazone alkylation. Asymmetric synthesis of α-aminoaldehydes

✍ Scribed by Alexandre Alexakis; Nathalie Lensen; Pierre Mangeney


Book ID
104225036
Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
243 KB
Volume
32
Category
Article
ISSN
0040-4039

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Asymmetric synthesis of uncommon α-amino
✍ Kiyoshi Tanaka; Mija Ahn; Yukari Watanabe; Kaoru Fuji 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 669 KB

For the purpose of practical preparations of a variety of enantiomerically pure uncommon ¢x-amino acids, alkylations of the chiral glycine equivalent 5, which possesses axially chiral binaphthol as an auxiliary, with several electrophiles were investigated. The alkylation proceeded smoothly in satis