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ChemInform Abstract: Chiral Aminal Templates: Diastereoselective Addition to Hydrazones; an Asymmetric Synthesis of α-Amino Aldehydes.

✍ Scribed by A. ALEXAKIS; N. LENSEN; J.-P. TRANCHIER; P. MANGENEY; J. FENEAU-DUPONT; J. P. DECLERCQ


Book ID
112024221
Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
26
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Asymmetric Addition
✍ O. NICAISE; S. DENMARK 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

Asymmetric Addition of Organometallic Reagents to Chiral α-Alkoxy Hydrazones. -The diastereoselective addition of three different types of nucleophilic reagents to three different α-alkoxy hydrazones is studied. With exception of the reation of the silylated hydrazone (Ib) with the heterogeneous 1: