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Chemoselective Boron–Carbon Bond Cleavage by Hydroboration of Borirenes

✍ Scribed by Holger Braunschweig; Thomas Herbst; Krzysztof Radacki; Gernot Frenking; Mehmet Ali Celik


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
555 KB
Volume
15
Category
Article
ISSN
0947-6539

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DimethyZphenyZsiZyZ-and diphenyZmethyZsiZyZ-vinyl carbon bonds are cleaved with ni3uqNF. DesiZyZation of I-phenyZthio-l-trimethyZsiZyZ-lalkenes in the presence of aldehyde moiety gives carbanion adducts. The affinity of fluoride ion for silicon has been well recognized and widely used for the cleava