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Carbon-bromine bond cleavage by electrooxidation of alkyl bromides

✍ Scribed by James Y. Becker; M. Münster


Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
177 KB
Volume
18
Category
Article
ISSN
0040-4039

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DimethyZphenyZsiZyZ-and diphenyZmethyZsiZyZ-vinyl carbon bonds are cleaved with ni3uqNF. DesiZyZation of I-phenyZthio-l-trimethyZsiZyZ-lalkenes in the presence of aldehyde moiety gives carbanion adducts. The affinity of fluoride ion for silicon has been well recognized and widely used for the cleava