Directed cleavage of carbon—tin bonds by palladium
✍ Scribed by J.William Suggs; Ken.S. Lee
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 920 KB
- Volume
- 299
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
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Oxidative cleavage of palladium-carbon bonds where a nucleophile replaces palladium (eq 1) occurs in catalytic systems utilizing palladium 2.3 and has recently been used to achieve oxy- RuD ArCOzOH ## HAH CH2C12 ) Acetoxypalladation of double bonds is known to be a trans-process. 12 Consequentl
Heteropolymolybdoacids, H 3 [PMo 12 O 40 ] and H 6 [P 2 Mo 18 O 62 ], catalyze the oxidative cleavage of C-Sn bond in the organotin derivatives of dibenzyldichlorotin (1) and tribenzylchlorotin (2) in the presence of dioxygen. Benzaldehyde is the major reaction product, accompanied by smaller amount