DimethyZphenyZsiZyZ-and diphenyZmethyZsiZyZ-vinyl carbon bonds are cleaved with ni3uqNF. DesiZyZation of I-phenyZthio-l-trimethyZsiZyZ-lalkenes in the presence of aldehyde moiety gives carbanion adducts. The affinity of fluoride ion for silicon has been well recognized and widely used for the cleava
Selective intramolecular cleavage of the carbon-silicon bond by palladium salts
✍ Scribed by Jean-Marc Valk; Jaap Boersma; Gerard van Koten
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 437 KB
- Volume
- 483
- Category
- Article
- ISSN
- 0022-328X
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Nickel peroxide selectively cleaves the s-carbon-nitrogen bond of glycine residues in dipeptide derivatives to give the corresponding amides, The glycine selectivity is attributable to preferential complexation of the reactant residue to nickel peroxide and subsequent reaction via a stable o~-centre
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