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Chemistry of C- Trimethylsilyl-Substituted Heterocarboranes. 25. Syntheses, Structures, and Reactivities of GeCl 3 -Substituted Half-Sandwich Germacarboranes, closo- 1-Ge-2-(SiMe 3 )-3-(R)-5-(GeCl 3 )-2,3-C 2 B 4 H 3 (R = SiMe 3 , Me, and H) †

✍ Scribed by Hosmane, Narayan S.; Yang, Jimin; Lu, Kai-Juan; Zhang, Hongming; Siriwardane, Upali; Islam, M. Safiqul; Thomas, Julie L. C.; Maguire, John A.


Book ID
126989175
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
193 KB
Volume
17
Category
Article
ISSN
0276-7333

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✍ Murugavel, Ramaswamy ;Voigt, Andreas ;Chandrasekhar, Vadapalli ;Roesky, Herbert 📂 Article 📅 1996 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 436 KB 👁 2 views

The silanediols RN(SiMe3)Si(OSiMe3)(0H)2 (R = 2,4,6-were characterized by means of mass, IR and NMR (lH and Me3C6H2 4, 2,6-Me2C6H3 5 , and 2,6-iPr2C6H3 6) were prepa-2gSi) spectroscopy. Additionally, the molecular structures of red by the reactions of the respective silanetriols RN(SiMe3)-4 and 7 we