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Silicon(IV) .pi.-complexes of C-(trimethylsilyl)-substituted carboranes. Syntheses of [(Me3Si) (R)C2B4H4]2Si and [(Me3Si)(Me)C2B4H4]SiH(R') [R = Me3Si, Me, or H; R' = H, or Cl]. Crystal structure of 2,2'-bis(trimethylsilyl)-3,3'-dimethyl-[1,1'-commo-bis(2,3-dicarba-1-sila-closo-heptaborane)]-(12)

✍ Scribed by Siriwardane, Upali; Islam, M. Safiqul; West, Thomas A.; Hosmane, Narayan S.; Maguire, John A.; Cowley, Alan H.


Book ID
126993711
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
768 KB
Volume
109
Category
Article
ISSN
0002-7863

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Silanediols Derived from Silanetriols. X
✍ Murugavel, Ramaswamy ;Voigt, Andreas ;Chandrasekhar, Vadapalli ;Roesky, Herbert πŸ“‚ Article πŸ“… 1996 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 436 KB πŸ‘ 2 views

The silanediols RN(SiMe3)Si(OSiMe3)(0H)2 (R = 2,4,6-were characterized by means of mass, IR and NMR (lH and Me3C6H2 4, 2,6-Me2C6H3 5 , and 2,6-iPr2C6H3 6) were prepa-2gSi) spectroscopy. Additionally, the molecular structures of red by the reactions of the respective silanetriols RN(SiMe3)-4 and 7 we