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Chemische Bindung in den cyclischen Anionen P64− und As64−: Synthese, Kristallstruktur und Elektronenlokalisierungsfunktion von {Rb([18]Krone-6)}2Rb2As6⋅6 NH3

✍ Scribed by Florian Kraus; Tobias Hanauer; Nikolaus Korber


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
452 KB
Volume
117
Category
Article
ISSN
0044-8249

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Chemical Bond in the Cyclic Anions P64−
✍ Florian Kraus; Tobias Hanauer; Nikolaus Korber 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 451 KB 👁 2 views

The bonding in the As 6 4À ion is studied in the unusually low-coordination environment provided by the compound {Rb[18]crown-6)} 2 Rb 2 As 6 •6 NH 3 . Theoretical analysis of the related P 6 4À ion indicates an unusual P¼P bond which contains major contributions from the lone pairs. Outside a highl