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ChemInform Abstract: π-Allylpalladium-Mediated Catalytic Synthesis of Functionalized Allenes.

✍ Scribed by Masamichi Ogasawara; Hisashi Ikeda; Tamio Hayashi

Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
31
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

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ChemInform Abstract: Novel Carbonyl-Dependent Regioselective Allylation via Diethylzinc-Mediated Umpolung of π-Allylpalladium.
✍ M. KIMURA; Y. OGAWA; M. SHIMIZU; M. SUEISHI; S. TANAKA; Y. TAMARU 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB

Novel Carbonyl-Dependent Regioselective Allylation via Diethylzinc-Mediated Umpolung of π-Allylpalladium. -The allylation of carbonyl compounds with allyl esters such as (I) in the presence of diethylzinc and catalytic Pd(0) is investigated. With benzaldehyde mainly α-allylation products (III) are