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ChemInform Abstract: α-Arylation of Ketones by Aryllead Triacetates. Effect of Methyl and Phenyl Substitution at the α-Position.

✍ Scribed by J. MORGAN; J. T. PINHEY; B. A. ROWE


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
28
Category
Article
ISSN
0931-7597

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✍ N. KOMIYA; S. NOJI; S.-I. MURAHASHI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB

Manganese Catalyzed Asymmetric Oxidation of Alkanes to Optically Active Ketones Bearing Asymmetric Center at the α-Position. -Symmetrical alkanes (II) and (IV) are oxidized with iodosobenzene/4phenylpyridine-N-oxide in the presence of catalytic chiral (salen)Mn(III) complexes (I) providing optically