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ChemInform Abstract: α-Acetoxysulfones as “Chiral Aldehyde” Equivalents.

✍ Scribed by Barry M. Trost; Matthew L. Crawley; Chul Bom Lee

Book ID
101904139
Publisher
John Wiley and Sons
Year
2000
Weight
34 KB
Volume
31
Category
Article
ISSN
0931-7597

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Behavior of Dioxolanones as Chiral Acyl Anion Equivalents. -Deprotonation of 1,3-dioxolan-4-ones [cf. (I)] and following alkylation gives products (III). Their flash vacuum pyrolysis yields ketones (IV) (with concomitant loss of CO and acetone) showing (I) to be acyl anion equivalents. Conjugate ad