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ChemInform Abstract: The Potential of Sulfimides as Chiral Acyl Anion Equivalents.

✍ Scribed by G. SMITH; T. J. SPAREY; P. C. TAYLOR

Book ID
112032602
Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
27
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Behavior of Dioxola
ChemInform Abstract: Behavior of Dioxolanones as Chiral Acyl Anion Equivalents.
✍ R. A. AITKEN; A. W. THOMAS πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 35 KB πŸ‘ 2 views

Behavior of Dioxolanones as Chiral Acyl Anion Equivalents. -Deprotonation of 1,3-dioxolan-4-ones [cf. (I)] and following alkylation gives products (III). Their flash vacuum pyrolysis yields ketones (IV) (with concomitant loss of CO and acetone) showing (I) to be acyl anion equivalents. Conjugate ad